Victory would be both the first major trophy for the England women’s team and the first football honour for the nation since the men’s 1966 World Cup win.
As well as making the team household names, a victory is also predicted to catapult women’s football in England to new heights.
But standing in the way again are Germany, who have won the competition eight times. They beat England 6-2 in the final of Euro 2009, the last time they played each other at the tournament.
The match is expected to be a sellout at Wembley, which has an 87,200 capacity for the Euros, with kick-off at 17:00 BST.
There is coverage across BBC television, radio and online, with millions expected to watch the match on the BBC.
The semi-final attracted a peak TV audience of 9.3m. England’s World Cup semi-final against the USA in 2019 holds the UK record for women’s football with 11.7m watching on the BBC.
Both teams have been the standout sides in the tournament, each conceding just one goal, and have shown their class to reach the showpiece at Wembley.
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The Lionesses justified their status as one of the pre-tournament favourites with a 4-0 semi-final thrashing of Sweden, ranked second in the world, while Germany, who came into the Euros as a bit of an unknown quantity, edged past France 2-1.
Not great, but then we described their record against Sweden as “shocking” and things didn’t go too badly in the semi-final.
But England will have to rewrite the record books once more if they are to triumph in the capital.
They have won just two of 27 meetings against Germany – though one of those came in their most recent meeting, in February.
England have lost more games (21) against the Germans than any other side, while they have been on the losing end in all four meetings at previous European Championships.
“These are the games you live for,” said England captain Leah Williamson.
“It’s a fairy-tale fixture with the history behind it. I think we have the two teams who have had the best tournaments in the final.
“Nobody ever has a home game where they don’t have an advantage. This is our national stadium so it’s familiar to us and the support we have had so far has been incredible. It’s an exciting thought that we have that on our side.”
Data analysts Nielsen Gracenote give England a 52% chance of success because of home advantage, saying Germany would have a 55% chance of winning at a neutral ground.
However, Germany are used to spoiling England’s party in the women’s and men’s games.
Manager Martina Voss-Tecklenburg said: “In the beginning, Wembley will be English and I hope it will belong to us at the end.
“We want to play our game, be courageous, aggressive, give it our all, play as a team. This has worked well so far.”
Battle of the bosses – Wiegman v Voss-Tecklenburg
History is waiting to be made by Sarina Wiegman and Voss-Tecklenburg.
England boss Wiegman’s record is formidable, winning all 11 games she has taken charge of at the Euros. She led the Netherlands to an unlikely triumph on home soil five years ago.
She is looking to repeat the feat with England on this occasion, in turn becoming the first coach to win the tournament with two different teams.